Modeling of light asymmetric rotors with unpaired electrons

Similarly the theory was (empirically) extended to include molecules with electronic effects.

[1][2]

References

  1. Charo, A. & De Lucia, F. C. The Millimeter and Submillimeter Spectrum of HO2: The Effects of the Unpaired Electronic Spin in a Light Asymmetric Rotor. J. Mol. Spectrosc. 94, 426-436 (1982).
  2. Bowman, W. C. & De Lucia, F. C. The Millimeter and Submillimeter Spectrum of NO2: A Study of Electronic Effects in a Nonsinglet Light Asymmetric Rotor. J. Chem. Phys. 77, 92-107 (1982).